Fluorinated (hetero)cycles via ring-closing metathesis of fluoride- and trifluoromethyl-functionalized olefins
until further notice
SourceTetrahedron Letters, 45, 5, (2004), pp. 959-963
Article / Letter to editor
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Synthetic Organic Chemistry
Solid State Chemistry
SubjectMolecular Materials; Synthetic Organic Chemistry
Ring-closing metathesis(RCM) has been shown to be a viable tool to incorporate fluoride and trifluoromethyl substituents in (hetero)cyclic ring systems. 2-Fluoroacrylamides were cyclized to the corresponding lactams, and trifluoromethyl- substituted olefins were cyclized to yield trifluoromethylated cyclopentenes, pyrrolines and a dihydrofuran derivative. (C) 2003 Elsevier Ltd. All rights reserved.
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