Reaction of AlEt2Cl with the diiminepyridine ligand: an unexpected product
SourceComptes Rendus Chimie, 7, 8-9, (2004), pp. 865-869
Article / Letter to editor
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Comptes Rendus Chimie
Reaction of AlEt2Cl with 2,6-bis(1-(2,6-diisopropylphenylimino)ethyl)pyridine offered an unexpected tricyclic complex, which was characterized by X-ray diffraction. The dimerisation reaction leading to this product has been studied by DFT calculations. This symmetry-forbidden cyclisation reaction was found to follow a biradical pathway with an unusual low energy barrier. (C) 2004 Academie des sciences. Published by Elsevier SAS. All rights reserved.
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