Porphyrin boxes as processive catalysts
Nijmegen : [S.n.]
Number of pages
Radboud University,, 27 februari 2007
Promotores : Nolte, R.J.M., Rowan, A.E. Co-promotor : Elemans, J.A.A.W.
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Physical Organic Chemistry
Physical Organic and Supramolecular Chemistry
SubjectPhysical Organic Chemistry
The synthesis and physical properties of cyclic tetrameric porphyrin-assemblies by both metal-directed self-assembly and dynamic combinatorial olefin metathesis is described. In order to create processive enzyme mimics, their ability to accommodate a range of polymers inside their cavity is investigated as well.
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