Deeper Insight into the Diels-Alder Reaction through the Activation Strain Model

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Title:	Deeper Insight into the Diels-Alder Reaction through the Activation Strain Model
Author(s):	Fernandez, I.; Bickelhaupt, F.M.
Publication year:	2016
Source:	Asian Journal of Chemistry, vol. 11, iss. 23, (2016), pp. 3297-3304
ISSN:	0970-7077
DOI:	http://dx.doi.org/10.1002/asia.201601203
Publication type:	Article / Letter to editor
Please use this identifier to cite or link to this item : https://hdl.handle.net/2066/166202
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Subject:	Theoretical Chemistry
Organization:	Theoretical Chemistry
Journal title:	Asian Journal of Chemistry
Volume:	vol. 11
Issue:	iss. 23
Page start:	p. 3297
Page end:	p. 3304
Abstract:	The Diels–Alder (DA) cycloaddition reaction has the ability to significantly increase molecular complexity regioselectively and stereospecifically in a single synthetic step. In this review it is discussed how the activation strain model of chemical reactivity reveals the physical factors that determine the course of Diels–Alder reactivity using recent, representative examples that cover a wide range of issues, such as the “endo-rule”, reactivity trends emerging from systematic variation in the reactants′ strain, and cycloaddition reactions involving relevant species in materials science (i.e., fullerenes, polycyclic aromatic hydrocarbons and nanotubes). More information can be found in the Focus Review by Fernández and Bickelhaupt on page 3297 in Issue 23