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Title: Needlelike morphology of aspartame
Author(s): Cuppen, H.M. (27143127X)
Eerd, A.R.T. van
Meekes, H.L.M. (298972719)
Publication year: 2004
Document type: Article / Letter to editor
Journal: Crystal Growth & Design
ISSN: 1528-7483
Volume: vol. 4
Issue: iss. 5
Start page: p. 989
End page: p. 997
Abstract: The needlelike morphology of aspartame form II-A is studied by means of Monte Carlo simulations. Growth simulations for all F faces show merely three faces with a nucleation barrier for growth: two side faces and one top face. Calculations of the energies involved in the growth for a few representative faces are in good agreement with these observations. For two of these faces, nuclei or steps could be formed without any energy cost. The simulations explain the needle shape of aspartame crystals and also the high supersaturation needed to nucleate the crystals.
Subject: Solid State Chemistry
Organization: Solid State Chemistry
Appears in Collections:Academic bibliography

Please use this identifier to cite or link to this item: http://hdl.handle.net/2066/60363

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