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| Title: | Processive rotaxane systems. Studies on the mechanism and control of the threading process |
| Author(s): | Ramos, P.H.
Coumans, R.G.E. (298116642)
Deutman, A.B.C. (298201992)
Smits, J.M.M. (297344781)
Gelder, R. de (100727905)
Elemans, J.A.A.W. (227901606)
Nolte, R.J.M. (14853919X)
Rowan, A.E. (298979357) |
| Publication year: | 2007 |
| Document type: | Article / Letter to editor |
| Journal: | Journal of the American Chemical Society |
| ISSN: | 0002-7863 |
| Volume: | vol. 129 |
| Issue: | iss. 17 |
| Start page: | p. 5699 |
| End page: | p. 5702 |
| Abstract: | The threading behavior of a zinc analogue of a previously reported processive manganese porphyrin catalyst onto a series of polymers of different lengths is reported. It is demonstrated that the speed of the threading process is determined by the opening of the cavity of the toroidal porphyrin host, which can be tuned with the help of axial ligands that coordinate to the metal center in the porphyrin. |
| Subject: | Molecular Materials
Physical Organic and Supramolecular Chemistry |
| Organization: | Bio-organic Chemistry
Physical Organic Chemistry
UMCN Extern
Molecular Materials |
| Organization (former): | Physical Organic and Supramolecular Chemistry
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| Appears in Collections: | Academic bibliography
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Please use this identifier to cite or link to this item:
http://hdl.handle.net/2066/36360
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